Lysosome ‐targeted potent half‐sandwich iridium(III) α‐diimine antitumor complexes
Applied Organometallic Chemistry, EarlyView. (Source: Applied Organometallic Chemistry)
Source: Applied Organometallic Chemistry - October 31, 2018 Category: Chemistry Authors: Deliang Kong, Lihua Guo, Meng Tian, Shumiao Zhang, Zhenzhen Tian, Huayun Yang, Ye Tian, Zhe Liu Source Type: research

Monodentate aminophosphine nickel(II) ‐ and palladium(II)‐catalyzed ethylene oligomerization and norbornene polymerization
Applied Organometallic Chemistry, EarlyView. (Source: Applied Organometallic Chemistry)
Source: Applied Organometallic Chemistry - October 31, 2018 Category: Chemistry Authors: Chunyong Rong, Weimin Li, Chen Tan Source Type: research

Facilitating a high ‐performance photocatalyst for Suzuki reaction: Palladium nanoparticles immobilized on reduced graphene oxide‐doped graphitic carbon nitride
Applied Organometallic Chemistry, EarlyView. (Source: Applied Organometallic Chemistry)
Source: Applied Organometallic Chemistry - October 31, 2018 Category: Chemistry Authors: Xiaohua Zhao, Jiateng Xie, Xin Liu, Xiang Liu Source Type: research

Hofmann N ‐alkylation of aniline derivatives with alcohols using ferric perchlorate immobilized on SiO2 as a catalyst through Box–Behnken experimental design
Applied Organometallic Chemistry, EarlyView. (Source: Applied Organometallic Chemistry)
Source: Applied Organometallic Chemistry - October 31, 2018 Category: Chemistry Authors: Mahdi Ghanimati, Masumeh Abdoli Senejani, Tahereh Momeni Isfahani, Mohammad Ali Bodaghifard Source Type: research

Facilitating a high ‐performance photocatalyst for Suzuki reaction: Palladium nanoparticles immobilized on reduced graphene oxide‐doped graphitic carbon nitride
Novel Pd/rGO ‐doped g‐C3N4 was prepared and used as an outstanding visible ‐light‐driven photocatalyst for Suzuki–Miyaura coupling reactions. The hybrid catalyst could be recycled using simple filtration and reused, while keeping similar catalytic activity for six successive reactions. We prepared a non ‐covalently coupled hybrid of reduced graphene oxide (rGO)‐doped graphitic carbon nitride (g‐C3N4) by freezing ‐assisted assembly and calcination. Fourier transform infrared, Raman and X‐ray photoelectron spectroscopies and transmission electron microscopy confirmed that rGO was incorporated into the bul...
Source: Applied Organometallic Chemistry - October 30, 2018 Category: Chemistry Authors: Xiaohua Zhao, Jiateng Xie, Xin Liu, Xiang Liu Tags: FULL PAPER Source Type: research

Hofmann N ‐alkylation of aniline derivatives with alcohols using ferric perchlorate immobilized on SiO2 as a catalyst through Box–Behnken experimental design
An efficient method for theN‐alkylation of poorly nucleophilic amines using ferric perchlorate immobilized on SiO2 as a catalyst is described. Ferric perchlorate adsorbed on silica gel (Fe(ClO4)3/SiO2) is an efficient and selective catalyst for theN‐alkylation of aromatic amines with alcohols to provide alkylated amines. An efficient method for theN‐alkylation of poorly nucleophilic amines using ferric perchlorate immobilized on SiO2 as a catalyst is described. Fe(ClO4)3 was prepared from mixing iron(III) hydroxide and perchloric acid and adsorbed on silica gel. The catalyst was characterized using various techniques...
Source: Applied Organometallic Chemistry - October 30, 2018 Category: Chemistry Authors: Mahdi Ghanimati, Masumeh Abdoli Senejani, Tahereh Momeni Isfahani, Mohammad Ali Bodaghifard Tags: FULL PAPER Source Type: research

Photochromism and decolorization controlled by auxiliary ligands of complexes derived from 1 ‐methyl‐4,4′‐bipyridinium cation
The influence of auxiliary ligands onthe molecular configuration and packing pattern has been explored, which plays a crucial role in determiningthe photochromism and decolourization process. Three 1 ‐methyl‐4,4′‐bipyridinium (MQ+) ‐based complexes, {[Cd(MQ)(p‐BDC)Br]⋅H2O}n (1), {[Cd(MQ)(m‐BDC)(H2O)Br] ⋅3H2O}n (2) and Cu(MQ)Br2 (3) (p‐H2BDC  = 1,4‐benzenedicarboxylic acid,m‐H2BDC  = 1,3‐benzenedicarboxylic acid), have been synthesized and structurally characterized. Compounds1 and2 are one ‐dimensional coordination polymers constituted of one coordinated MQ+ cation, one coordinated Br− ion...
Source: Applied Organometallic Chemistry - October 29, 2018 Category: Chemistry Authors: Jin ‐jian Liu Tags: FULL PAPER Source Type: research

Novel Fe3O4/hydroxyapatite/ β‐cyclodextrin nanocomposite adsorbent: Synthesis and application in heavy metal removal from aqueous solution
Novel nano magnetic composite was synthesized and used in heavy metal removal from aqueous solution. The characterization methods confirmed the successful synthesis of the adsorbent. The maximum adsorbent capacity of the adsorbent for Cd2+ and CU2+ were 100.00 and 66.66 mg/g, respectively which showed that it is a potential candidate for heavy metal removal applications. The increased global concern on environmental protection has made researchers focus their attention on new and more efficient methods of pollutant removal. In this research, novel nanocomposite adsorbents,i.e., magnetic hydroxyapatite (Fe3O4@HA) and magnet...
Source: Applied Organometallic Chemistry - October 29, 2018 Category: Chemistry Authors: Ali Ansari, Shahrokh Vahedi, Omid Tavakoli, Mehdi Khoobi, Mohammad Ali Faramarzi Tags: FULL PAPER Source Type: research

Novel Fe3O4/hydroxyapatite/ β‐cyclodextrin nanocomposite adsorbent: Synthesis and application in heavy metal removal from aqueous solution
Applied Organometallic Chemistry, EarlyView. (Source: Applied Organometallic Chemistry)
Source: Applied Organometallic Chemistry - October 29, 2018 Category: Chemistry Authors: Ali Ansari, Shahrokh Vahedi, Omid Tavakoli, Mehdi Khoobi, Mohammad Ali Faramarzi Source Type: research

Photochromism and decolorization controlled by auxiliary ligands of complexes derived from 1 ‐methyl‐4,4′‐bipyridinium cation
Applied Organometallic Chemistry, EarlyView. (Source: Applied Organometallic Chemistry)
Source: Applied Organometallic Chemistry - October 29, 2018 Category: Chemistry Authors: Jin ‐jian Liu Source Type: research

Synthesis, structural characterization, density functional theory (B3LYP) calculations, thermal behaviour, docking and antimicrobial activity of 4 ‐amino‐5‐(heptadec‐8‐en‐1‐yl)‐4H‐1,2,4‐triazole‐3‐thiol and its metal chelates
Biological activity of ligand and its metal chelates. The structure of prepared triazole ligand 4 ‐amino‐5‐(heptadec‐8‐en‐1‐yl)‐4H‐1,2,4‐triazole‐3‐thiol and its coordination behaviour towards transition metal ions Ni (II), Co (II), Fe (III), Cd (II) and Cu (II) have been studied using magnetic measurements, elemental analyses and electronic, Fourier transform infrared and1H NMR spectroscopies. The thermal behaviours of the triazole ligand and its chelates were investigated and their thermal decomposition possibilities are proposed. The stages of all thermal decompositions are discussed. The Gaussia...
Source: Applied Organometallic Chemistry - October 25, 2018 Category: Chemistry Authors: Ehab M. Zayed, Mohamed A. Zayed, Hayam A. Abd El Salam, Galal A.M. Nawwar Tags: FULL PAPER Source Type: research

Metal –organic framework‐derived cobalt and nitrogen co‐doped porous carbon with four‐coordinated Co–Nx for efficient acetylene hydrochlorination
Introducing a small amount of Co to N ‐doped carbon can significantly improve the catalytic activity for acetylene hydrochlorination due to the fact that the generated Co‐N4 has a stronger ability to adsorb and activate acetylene. Industrial production of vinyl chloride through acetylene hydrochlorination is a dominating technique in coal ‐rich areas, but its development is severely restricted by the use of toxic mercury chloride (HgCl2) catalyst. Inspired by the fact that doped carbon materials active in acetylene hydrochlorination often have good performance in the oxygen reduction reaction, a series of cobalt and ...
Source: Applied Organometallic Chemistry - October 25, 2018 Category: Chemistry Authors: Xiaobin Dong, Chaoyue Zhao, Qingxin Guan, Wei Li, Xiufang Xu Tags: FULL PAPER Source Type: research

Metal –organic framework‐derived cobalt and nitrogen co‐doped porous carbon with four‐coordinated Co–Nx for efficient acetylene hydrochlorination
Applied Organometallic Chemistry, EarlyView. (Source: Applied Organometallic Chemistry)
Source: Applied Organometallic Chemistry - October 25, 2018 Category: Chemistry Authors: Xiaobin Dong, Chaoyue Zhao, Qingxin Guan, Wei Li, Xiufang Xu Source Type: research

Synthesis, structural characterization, density functional theory (B3LYP) calculations, thermal behaviour, docking and antimicrobial activity of 4 ‐amino‐5‐(heptadec‐8‐en‐1‐yl)‐4H‐1,2,4‐triazole‐3‐thiol and its metal chelates
Applied Organometallic Chemistry, EarlyView. (Source: Applied Organometallic Chemistry)
Source: Applied Organometallic Chemistry - October 25, 2018 Category: Chemistry Authors: Ehab M. Zayed, Mohamed A. Zayed, Hayam A. Abd El Salam, Galal A.M. Nawwar Source Type: research

Facile fabrication of BUC ‐21/g‐C3N4 composites and their enhanced photocatalytic Cr(VI) reduction performances under simulated sunlight
Applied Organometallic Chemistry, EarlyView. (Source: Applied Organometallic Chemistry)
Source: Applied Organometallic Chemistry - October 25, 2018 Category: Chemistry Authors: Xiao ‐Hong Yi, Fu‐Xue Wang, Xue‐Dong Du, Peng Wang, Chong‐Chen Wang Source Type: research