Strategies for development of optogenetic systems and their applications
Publication date: Available online 14 November 2016 Source:Journal of Photochemistry and Photobiology C: Photochemistry Reviews Author(s): M. Endo, T. Ozawa It has become clear that biological processes are highly dynamic and heterogeneous within and among cells. Conventional analytical tools and chemical or genetic manipulations are unsuitable for dissecting the role of their spatiotemporally dynamic nature. Recently, optical control of biomolecular signaling, a technology called “optogenetics,” has gained much attention. The technique has enabled spatial and temporal regulation of specific signaling pathways both...
Source: Journal of Photochemistry and Photobiology C: Photochemistry Reviews - November 14, 2016 Category: Chemistry Source Type: research

Utilization of Microflow Reactors to Carry Out Synthetically Useful Organic Photochemical Reactions
Publication date: Available online 6 November 2016 Source:Journal of Photochemistry and Photobiology C: Photochemistry Reviews Author(s): Kazuhiko Mizuno, Yasuhiro Nishiyama, Takuya Ogaki, Kimitada Terao, Hiroshi Ikeda, Kiyomi Kakiuchi This review focuses on recent advances that have been made in conducting synthetically useful organic photochemical reactions by using microflow reactors. Attention is given to the utilization of this technique in the “scale-up” of a variety of photochemical processes including intermolecular photocycloadditions, intramolecular photocycloadditions and photocyclizations, photoaddi...
Source: Journal of Photochemistry and Photobiology C: Photochemistry Reviews - November 6, 2016 Category: Chemistry Source Type: research

Evolution of 2, 3 ′−bipyridine class of cyclometalating ligands as efficient phosphorescent iridium(III) emitters for applications in organic light emitting diodes
Publication date: Available online 5 November 2016 Source:Journal of Photochemistry and Photobiology C: Photochemistry Reviews Author(s): M.L.P. Reddy, K.S. Bejoymohandas Nowadays, the design and development of novel phosphorescent iridium(III) complexes for various optoelectronic applications is a well−recognized area of research. The fascinating photophysical properties of iridium(III) compounds are strongly influenced by the spin−orbit coupling exerted by the iridium(III) core, usually resulting in intense emissions with short excited−state lifetimes, which can be precisely controlled with the aid of molecular...
Source: Journal of Photochemistry and Photobiology C: Photochemistry Reviews - November 4, 2016 Category: Chemistry Source Type: research

Toxicity, Phototoxicity and Biocidal Activity of Nanoparticles Employed in Photocatalysis
Publication date: Available online 29 September 2016 Source:Journal of Photochemistry and Photobiology C: Photochemistry Reviews Author(s): Elsa Friehs, Yamen AlSalka, Rebecca Jonczyk, Antonina Lavrentieva, André Jochums, Johanna-Gabriela Walter, Frank Stahl, Thomas Scheper, Detlef Bahnemann Photocatalytically active nanoparticles (PCNPs) are extensively investigated for numerous environmental and energy related applications. Independent from their photocatlytic properties, many PCNPs are established as additives for industrial materials (e.g. paintings or coatings) or even in foods, textiles and cosmetics, whi...
Source: Journal of Photochemistry and Photobiology C: Photochemistry Reviews - September 28, 2016 Category: Chemistry Source Type: research

Searching for facet-dependent photoactivity of shape-controlled anatase TiO2
Publication date: Available online 28 July 2016 Source:Journal of Photochemistry and Photobiology C: Photochemistry Reviews Author(s): Michela Maisano, Maria Vittoria Dozzi, Elena Selli Improving the performance of mostly employed anatase TiO2 photocatalysts by properly controlling their crystal shape represents a big challenge to improve their efficiency in photocatalytic applications. After the synthesis, reported in 2008, of anatase microcrystals enriched in high-energy {001} facets, many efforts have been made aimed at tuning the crystal morphology of anatase, by means of either fluorine-mediated or more envi...
Source: Journal of Photochemistry and Photobiology C: Photochemistry Reviews - July 28, 2016 Category: Chemistry Source Type: research

Aggregation-induced phosphorescence enhancement (AIPE) based on transition metal complexes —An overview
Publication date: June 2015 Source:Journal of Photochemistry and Photobiology C: Photochemistry Reviews, Volume 23 Author(s): Veerasamy Sathish, Arumugam Ramdass, Pounraj Thanasekaran, Kuang-Lieh Lu, Seenivasan Rajagopal Aggregation-induced emission (enhancement) (AIE(E)) is an extraordinary phenomenon in the field of photochemistry and offers a new platform for researchers to investigate the light-emitting process from nanoaggregates. Non- or weakly emissive molecules are induced to emit efficiently through nanoaggregate formation, which are referred to as aggregation-induced emission (AIE) and aggregation-i...
Source: Journal of Photochemistry and Photobiology C: Photochemistry Reviews - July 20, 2016 Category: Chemistry Source Type: research

Excited-state intramolecular proton transfer in 2 ′-(2′-hydroxyphenyl)imidazo[1,2-a]pyridines
Publication date: Available online 3 June 2016 Source:Journal of Photochemistry and Photobiology C: Photochemistry Reviews Author(s): Anton J. Stasyuk, Piotr J. Cywiński, Daniel T. Gryko The key observation made by Acuña revealed the unusual optical properties of previously unknown 2-(2′-hydroxyphenyl)imidazo[1,2-a]pyridines (HPIPs). Although structurally similar to 2′-(2′-hydroxyphenyl)benzoxazoles and 2-(2′-hydroxyphenyl)benzimidazoles, 2-(2′-hydroxyphenyl)imidazo[1,2-a]pyridines exhibit strikingly different optical properties, especially in the solid state. The luminescence color of HPIPs depends o...
Source: Journal of Photochemistry and Photobiology C: Photochemistry Reviews - July 20, 2016 Category: Chemistry Source Type: research

In situ patterning and controlling living cells by utilizing femtosecond laser
Publication date: Available online 9 July 2016 Source:Journal of Photochemistry and Photobiology C: Photochemistry Reviews Author(s): Kazunori Okano, Hsin-Yun Hsu, Yaw-Kuen Li, Hiroshi MasuharaGraphical abstract (Source: Journal of Photochemistry and Photobiology C: Photochemistry Reviews)
Source: Journal of Photochemistry and Photobiology C: Photochemistry Reviews - July 9, 2016 Category: Chemistry Source Type: research

Excited-state intramolecular proton transfer in 2′-(2′-hydroxyphenyl)imidazo[1,2-a]pyridines
Publication date: Available online 3 June 2016 Source:Journal of Photochemistry and Photobiology C: Photochemistry Reviews Author(s): Anton J. Stasyuk, Piotr J. Cywiński, Daniel T. Gryko The key observation made by Acuña revealed the unusual optical properties of previously unknown 2-(2′-hydroxyphenyl)imidazo[1,2-a]pyridines (HPIPs). Although structurally similar to 2′-(2′-hydroxyphenyl)benzoxazoles and 2-(2′-hydroxyphenyl)benzimidazoles, 2-(2′-hydroxyphenyl)imidazo[1,2-a]pyridines exhibit strikingly different optical properties, especially in the solid state. The luminescence color of HPIPs depends o...
Source: Journal of Photochemistry and Photobiology C: Photochemistry Reviews - July 4, 2016 Category: Chemistry Source Type: research

Solvothermal alcoholysis synthesis of hierarchical TiO2 with enhanced activity in environmental and energy photocatalysis
Publication date: Available online 23 June 2016 Source:Journal of Photochemistry and Photobiology C: Photochemistry Reviews Author(s): Zhenfeng Bian, Jian Zhu, Hexing Li Titanium dioxide (TiO2) represents the most widely used semiconductor photocatalysts and photovoltaics owing to its stability, low cost, and nontoxicity properties. The performances of TiO2 highly governed by the physical and chemical properties such as specific surface area, particle size, porous structure, exposed crystal plane, and surface chemistry etc. Synthesis technology plays a key role in determining the structural characteristics by con...
Source: Journal of Photochemistry and Photobiology C: Photochemistry Reviews - July 4, 2016 Category: Chemistry Source Type: research

Developments in and Prospects for Photocathodic and Tandem Dye-sensitized Solar Cells
Publication date: Available online 30 June 2016 Source:Journal of Photochemistry and Photobiology C: Photochemistry Reviews Author(s): Andrew Nattestad, Ishanie Perera, Leone Spiccia Third generation photovoltaics are based on the concept of providing high conversion efficiencies with low device production costs. As such, second generation concepts, such as Dye-sensitized Solar Cells (DSCs), serve as a good starting point for the development of these new devices. Tandem DSC devices are one example of such a concept, and can be constructed using two photoactive electrodes (one photoanode and one photocathode) insi...
Source: Journal of Photochemistry and Photobiology C: Photochemistry Reviews - July 4, 2016 Category: Chemistry Source Type: research

Enhancement of Catalytic Activity and Oxidative Ability for Graphitic Carbon Nitride
Publication date: Available online 16 June 2016 Source:Journal of Photochemistry and Photobiology C: Photochemistry Reviews Author(s): Wenjun Jiang, Wenjiao Luo, Jun Wang, Mo Zhang, Yongfa Zhu Growing awareness of energy conservation and pollutant elimination has been raised on graphitic carbon nitride (g-C3N4) recently thanks to the tunable electronic structure and excellent physicochemical stability of g-C3N4. This review summarizes the recent progress of g-C3N4 based materials regarding the catalytic activity improvement and oxidative ability enhancement. The former includes nanostructure design at differe...
Source: Journal of Photochemistry and Photobiology C: Photochemistry Reviews - June 15, 2016 Category: Chemistry Source Type: research

High Performance Arylamine-Based Metallated and Metal-Free Organic Photosensitizers for Dye-Sensitized Solar Cells
Publication date: Available online 3 June 2016 Source:Journal of Photochemistry and Photobiology C: Photochemistry Reviews Author(s): Cheuk-Lam Ho, Wai-Yeung Wong Increasing energy demands and environmental concerns about global warming have led to a greater focus on the development of renewable energy sources. Dye-sensitized solar cells (DSSCs) have attracted considerable attention in recent years as they offer the possibility of low-cost conversion of photovoltaic energy. In particular, triarylamine functionalized organic photosensitizers show high molar absorption coefficients in the visible spectral region, goo...
Source: Journal of Photochemistry and Photobiology C: Photochemistry Reviews - June 3, 2016 Category: Chemistry Source Type: research

Excited-state intramolecular proton transfer in 2'-(2'-hydroxyphenyl)imidazo[1,2-a]pyridines
Publication date: Available online 3 June 2016 Source:Journal of Photochemistry and Photobiology C: Photochemistry Reviews Author(s): Anton J. Stasyuk, Piotr J. Cywiński, Daniel T. Gryko The key observation made by Acuña revealed the unusual optical properties of previously unknown 2-(2'-hydroxyphenyl)imidazo[1,2-a]pyridines (HPIPs). Although structurally similar to 2'-(2'-hydroxyphenyl)benzoxazoles and 2-(2'-hydroxyphenyl)benzimidazoles, 2-(2'-hydroxyphenyl)imidazo[1,2-a]pyridines exhibit strikingly different optical properties, especially in the solid state. The luminescence color of HPIPs depends on the poly...
Source: Journal of Photochemistry and Photobiology C: Photochemistry Reviews - June 3, 2016 Category: Chemistry Source Type: research

Optical sensing of anions using C3v-symmetric tripodal receptors
Publication date: Available online 20 May 2016 Source:Journal of Photochemistry and Photobiology C: Photochemistry Reviews Author(s): Suban K. Sahoo, Gi-Dong Kim, Heung-Jin Choi The ubiquitous nature of anions has gained a bourgeoning interest among the supramolecular chemists to develop artificial receptors for the selective recognition and sensing of bioactive anions. Many excellent linear, dipodal, tripodal and multipodal anion receptors have been reported in the last two decades to recognize and detect anions of diverse geometry selectively. This review was narrated with the aim to summarize the C 3v-symmetri...
Source: Journal of Photochemistry and Photobiology C: Photochemistry Reviews - May 20, 2016 Category: Chemistry Source Type: research