Synthesis, Characterization, and Reactivity of a Hypervalent ‐Iodine‐Based Nitrooxylating Reagent

Synthesis, Characterization, and Reactivity of a Hypervalent ‐Iodine‐Based Nitrooxylating ReagentRoxan Calvo Antoine Le Tellier Dr. Thomas Nauser Dr. David Rombach Darryl Nater Dr. Dmitry KatayevOrganic nitrate esters were synthesized through the use of a hypervalent ‐iodine‐based nitrooxylating reagent. Its versatile reactivity under various reaction conditions is demonstrated in the synthesis of nitrooxylated β‐keto esters, 1,3‐diketones, malonates, and oxindoles under mild conditions.

Source: Organometallic Current - August 5, 2020 Category: Chemistry Tags: Hypervalent Iodine Reagents Nitration Source Type: blogs