Antiwettability enhancement of PVDF-HFP membrane via superhydrophobic modification by SiO2 nanoparticles

In this study, a superhydrophobic polyvinylidene fluoride-co-hexafluoropropylene membrane was synthesized via a simple and facile nonsolvent-induced phase inversion process. Hydrophobic nano-SiO2 particles were used as solvent additives to improve the wetting resistance of the membrane. The results revealed that blended nano-SiO2 membranes exhibited enhanced surface hydrophobicity in terms of water contact angle. Such improvement was attributed to the enhancement of surface roughness via the formation of hierarchical multilevel protrusions. Besides, the embedment of nanoparticles in polymer spherulitic globules also contributed to the reduction in surface energy of the membrane. As a result, the blended nano-SiO2 membrane achieved superhydrophobicity with a water contact angle of up to 151°.
Source: Comptes Rendus Chimie - Category: Chemistry Source Type: research