Synthesis, characterization and catalytic performance of core ‐shell structure magnetic Fe3O4/P(GMA‐EGDMA)‐NH2/HPG‐COOH‐Pd catalyst

Fe3O4/P(GMA ‐EGDMA)‐NH2/HPG ‐COOH‐Pd microspheres are prepared with hyperbranched polymer layer, which can convent 4‐nitrophenol to 4‐aminophenol efficiently, and whose catalytic efficiency can still maintain up to 86% after eight cycles catalytic experiments. A strategy has been developed for the synthesis, characterization and catalysis of magnetic Fe3O4/P(GMA ‐EGDMA)‐NH2/HPG ‐COOH‐Pd core‐shell structure supported catalyst. The P(GMA‐EGDMA) polymer layer was coated on the surface of hollow magnetic Fe3O4 microspheres through the effect of KH570. The core ‐shell magnetic Fe3O4/P(GMA ‐EGDMA) modified by ‐NH2 could be grafted with HPG. Then, the hyperbranched glycidyl (HPG) with terminal ‐OH were modified by ‐COOH and adsorbed Pd nanoparticles. The hyperbranched polymer layer not only protected the Fe3O4 magnetic core from acid –base substrate corrosion, but also provided a number of functional groups as binding sites for Pd nanoparticles. The prepared catalyst was characterized by UV–vis, TEM, SEM, FTIR, TGA, ICP‐OES, BET, XRD, DLS and VSM. The catalytic tests showed that the magnetic Fe3O4/P(GMA ‐EGDMA)‐NH2/HPG ‐COOH‐Pd catalyst had excellent catalytic performance and retained 86% catalytic efficiency after 8 consecutive cycles.

Source: Applied Organometallic Chemistry - November 19, 2018 Category: Chemistry Authors: Mingliang Ma, Yuying Yang, Dili Liao, Ping Lyu, Jinwei Zhang, Jianli Liang, Lizhi Zhang Tags: FULL PAPER Source Type: research