Influence of imide functionalized organo ‐modified Mg‐Al layered double hydroxide on the thermal and mechanical properties of new aliphatic‐aromatic poly (amide‐imide)

Two new series nanocomposites were prepared from a new synthesized poly(amideimide) and two organo modified LDH. The effects of organic modifier structure on the thermal and mechanical properties of resulted poly(amide ‐imide)/Mg‐Al LDH nanocomposites were investigated. A new dicarboxylic acid modified Mg ‐Al LDH (DLDH) containing imide groups was prepared and its effects on the thermal and mechanical properties of the new synthesized aliphatic‐aromatic poly (amide‐imide) (PAI) were investigated via preparation of PAI/nanocomposite films by solution casting method. The results of X‐ray diffra ction (XRD), field emission‐scanning electron microscopy (FE‐SEM) and transmission electron microscopy (TEM) showed a uniform dispersion for LDH layers into the PAI matrix. For comparison, the effects of polyacrylic acid‐co‐poly‐2‐acrylamido‐ 2‐methylpropanesulfonic acid (PAMPS‐co‐ PAA) modified Mg‐Al LDH (ALDH) on the PAI properties were also studied. The thermogravimetric analysis (TGA) results exhibited that the temperature at 5 mass% loss (T5) increased from 277  °C to 310 °C for nanocomposite containing 2 mass% of DLDH, while T5 for nanocomposite containing 2 mass% of ALDH increased to 320  °C, along with the more enhancement of char residue compared to the neat PAI. According to the tensile test results, with 5 mass% DLDH loading in the PAI matrix, the tensile strength increased from 51.6 to 70.8 MPa along with an increase in Young's modulus...
Source: Applied Organometallic Chemistry - Category: Chemistry Authors: Tags: FULL PAPER Source Type: research