Synthesis of S, N co-doped porous carbons from polybenzoxazine for CO2 capture

Publication date: October 2018Source: New Carbon Materials, Volume 33, Issue 5Author(s): Zu-er JIN, Jian-long WANG, Ri-jie ZHAO, Tao-tao GUAN, Dong-dong ZHANG, Kai-xi LIAbstractS, N co-doped porous carbons were synthesized from polybenzoxazine through solidification, carbonization and KOH activation using 4-cyanophenol, thiourea and formaldehyde as the monomers and a triblock copolymer (Pluronic F127) as a soft template. The samples were characterized by FT-IR, SEM, N2 adsorption, elemental analysis and XPS. Results indicate that the activated samples had high surface areas of 1 511. 6-2 385. 1 m2 g−1 with a large number of micropores and abundant sulfur and nitrogen functionalities. The templated samples had apparently lower contents of sulfur, nitrogen and oxygen than the un-templated ones due to the easy escape of volatile sulfur, nitrogen and oxygen compounds during carbonization and KOH activation. CO2 uptake had contributions from both physical and chemical adsorption and depended on the volume of narrow micropores less than 0.8 nm and the numbers of basic sulfur and nitrogen functional groups. The un-templated sample activated at 600 °C had the highest CO2 uptakes of 6.96 and 4.55 mmol g−1 under 1 bar at 0 and 25 °C, respectively, and was highly selective for CO2/N2 separation and had a high recyclable stability for CO2 capture.Graphical abstractSIN co-doped porous carbons for adsorbing CO2 were prepared based on polybenzoxazine using 4-cyanophenol, thiourea and ...

Source: New Carbon Materials - October 30, 2018 Category: Chemistry Source Type: research