Recent progress on the characterization of the high-pressure behaviour of AVO4 orthovanadates

Publication date: August 2018Source: Progress in Materials Science, Volume 97Author(s): Daniel Errandonea, Alka B. GargAbstractAVO4 orthovanadates are materials of fundamental and technological importance due to the large variety of functional properties exhibited by them. These materials have potential applications such as scintillators, thermophosphors, photocatalysts, and cathodoluminescence materials among others. They are also used as laser-host crystals. Studies at high pressures and temperatures are helpful for understanding the physical properties of the solid state, in particular, the phase behaviour of AVO4 materials. For instance, they have contributed to the understanding of the macroscopic properties of orthovanadates in terms of microscopic mechanisms. A great progress has been made in the last decade towards the study of the pressure-effects on the structural, vibrational, and electronic properties of AVO4 compounds. Thanks to the combination of experimental and theoretical studies, novel metastable structures with interesting physical properties have been discovered and the high-pressure structural sequence followed by AVO4 oxides has been understood. In this article, we will review high-pressure studies carried out on the phase behaviour of different AVO4 compounds. The studied materials include rare-earth orthovanadates and other compounds; for example, BiVO4, FeVO4, CrVO4, and InVO4. In particular, we will focus on discussing the results obtained by differe...
Source: Progress in Materials Science - Category: Materials Science Source Type: research