Rhodium ‐Catalyzed Cyclization of O,ω‐Unsaturated Alkoxyamines: Formation of Oxygen‐Containing Heterocycles

AngewchemRhodium ‐Catalyzed Cyclization of O,ω‐Unsaturated Alkoxyamines: Formation of Oxygen‐Containing Heterocycles: O, ω‐Unsaturated N‐tosyl alkoxyamines undergo unexpected RhIII‐catalyzed intramolecular cyclization by oxyamination to produce oxygen‐containing heterocycles. Mechanistic studies show that an aziridine...

Source: Organometallic Current - December 11, 2017 Category: Chemistry Tags: Cyclization Rh Catalyzed Source Type: blogs