Intramolecular Acetyl Transfer to Olefins by Catalytic C −C Bond Activation of Unstrained Ketones

AngewchemIntramolecular Acetyl Transfer to Olefins by Catalytic C −C Bond Activation of Unstrained Ketones: A rhodium ‐catalyzed intramolecular acetyl‐group transfer has been achieved through a “cut and sew” process. The challenge arises from the existence of different competitive pathways. Preliminary success...

Source: Organometallic Current - December 11, 2017 Category: Chemistry Tags: C-C bond activation Rh Catalyzed Source Type: blogs