Fluorinated Vinylsilanes from the Copper ‐Catalyzed Defluorosilylation of Fluoroalkene Feedstocks

AngewchemFluorinated Vinylsilanes from the Copper ‐Catalyzed Defluorosilylation of Fluoroalkene Feedstocks: Herein, a copper ‐catalyzed C−F bond defluorosilylation reaction of tetrafluoroethylene and other polyfluoroalkenes is described. Mechanistic studies, based on a series of stoichiometric reactions with...

Source: Organometallic Current - December 8, 2017 Category: Chemistry Tags: C-F Bond Activation Cu catalyzed Source Type: blogs