Divergent Total Syntheses of ( −)‐Daphnilongeranin B and (−)‐Daphenylline

AngewchemDivergent Total Syntheses of ( −)‐Daphnilongeranin B and (−)‐Daphenylline: ( −)‐Daphnilongeranin B and (−)‐daphenylline are two hexacyclic Daphniphyllum alkaloids, each containing a complex cagelike backbone. Described herein are the first asymmetric total synthesis of (−)‐daphnilongeranin B...

Source: Organometallic Current - December 8, 2017 Category: Chemistry Tags: Natural products Total synthesis Source Type: blogs