Catalytic Dibenzocyclooctene Synthesis via Cobalt(III) –Carbene Radical and ortho‐Quinodimethane Intermediates

AngewchemCatalytic Dibenzocyclooctene Synthesis via Cobalt(III) –Carbene Radical and ortho‐Quinodimethane Intermediates: The metalloradical activation of ortho ‐benzallylaryl N‐tosyl hydrazones with [Co(TPP)] (TPP=tetraphenylporphyrin) as the catalyst enabled the controlled exploitation of the single‐electron reactivity of...

Source: Organometallic Current - December 8, 2017 Category: Chemistry Tags: Co catalyzed Radical Reactions Source Type: blogs