Aluminabenzene –Rh and −Ir Complexes: Synthesis, Structure, and Application toward Catalytic C–H Borylation

JacsAluminabenzene –Rh and −Ir Complexes: Synthesis, Structure, and Application toward Catalytic C–H Borylation: Aluminabenzene –rhodium and −iridium complexes were synthesized, in which the aluminum atom played as a proximal Lewis acidic site. Based on their structural analysis, aluminabenzene ligand could coordinate to Rh and Ir as a η5-pentadienyl ligand.

Source: Organometallic Current - December 5, 2017 Category: Chemistry Tags: Borylation Ir catalyzed Rh Catalyzed Source Type: blogs