Radical Cyclization of Alkene ‐Tethered Ketones Initiated by Hydrogen‐Atom Transfer

AngewchemRadical Cyclization of Alkene ‐Tethered Ketones Initiated by Hydrogen‐Atom Transfer: An unprecedented C −C coupling reaction between alkenes and ketones by hydrogen‐atom transfer, using Fe(acac)3 and PhSiH3 in EtOH, is described. This mild protocol features high site selectivity and allows...

Source: Organometallic Current - December 4, 2017 Category: Chemistry Tags: Radical Cyclization Source Type: blogs