Enantioselective Rhodium ‐Catalyzed Coupling of Arylboronic Acids, 1,3‐Enynes, and Imines by Alkenyl‐to‐Allyl 1,4‐Rhodium(I) Migration

AngewchemEnantioselective Rhodium ‐Catalyzed Coupling of Arylboronic Acids, 1,3‐Enynes, and Imines by Alkenyl‐to‐Allyl 1,4‐Rhodium(I) Migration: A chiral rhodium complex catalyzes the highly enantioselective coupling of arylboronic acids, 1,3 ‐enynes, and imines to give homoallylic sulfamates. The key step is the generation of allylrhodium(I) species...

Source: Organometallic Current - November 28, 2017 Category: Chemistry Tags: Enantioselective Rh Catalyzed Source Type: blogs