Enantioselective and Collective Total Syntheses of Xanthanolides

AngewchemEnantioselective and Collective Total Syntheses of Xanthanolides: An enantioselective synthesis of (+) ‐8‐epi‐xanthatin hinging on a chiral phosphoric acid catalyzed tandem allylboration/lactonization reaction is reported. With (+)‐8‐epi‐xanthatin as the precursor, the...

Source: Organometallic Current - November 28, 2017 Category: Chemistry Tags: Enantioselective Natural products Total synthesis Source Type: blogs