Microwave ‐Assisted Synthesis of Heterocycles by Rhodium(III)‐Catalyzed Annulation of N‐Methoxyamides with α‐Chloroaldehydes

AngewchemMicrowave ‐Assisted Synthesis of Heterocycles by Rhodium(III)‐Catalyzed Annulation of N‐Methoxyamides with α‐Chloroaldehydes: α‐Chloroaldehydes have been used as alkyne equivalents in rhodium‐catalyzed syntheses of isoquinolones and 3,4‐dihydroisoquinolins starting from N‐methoxyamides. Compared to the existing technology, a...

Source: Organometallic Current - November 23, 2017 Category: Chemistry Tags: annulation microwave Rh Catalyzed Source Type: blogs