Isoquinoline ‐1‐Carboxylate as a Traceless Leaving Group for Chelation‐Assisted Glycosylation under Mild and Neutral Reaction Conditions

AngewchemIsoquinoline ‐1‐Carboxylate as a Traceless Leaving Group for Chelation‐Assisted Glycosylation under Mild and Neutral Reaction Conditions: Glycosyl isoquinoline ‐1‐carboxylate was developed as a novel benchtop stable and readily available glycosyl donor. The glycosylation reaction was promoted by the inexpensive Cu(OTf)2 salt under mild reaction...
Source: Organometallic Current - Category: Chemistry Tags: Cu catalyzed Glycosylation Source Type: blogs