Visible ‐Light‐Driven Palladium‐Catalyzed Radical Alkylation of C−H Bonds with Unactivated Alkyl Bromides

AngewchemVisible ‐Light‐Driven Palladium‐Catalyzed Radical Alkylation of C−H Bonds with Unactivated Alkyl Bromides: Reported herein is a novel visible ‐light photoredox system with Pd(PPh3)4 as the sole catalyst for the realization of the first direct cross‐coupling of C(sp3)−H bonds in N‐aryl tetrahydroisoquinolines...

Source: Organometallic Current - November 9, 2017 Category: Chemistry Tags: Alkylation Pd Catalyzed Visible light Source Type: blogs