Synthesis of nitrogen-doped graphitic carbon nanocapsules from a poly(ionic liquid) for CO2 capture

Publication date: August 2017 Source:New Carbon Materials, Volume 32, Issue 4 Author(s): Lei Liu, Juan Lu, Yi-xin Zhang, Meng Liu, Yi-feng Yu, Ai-bing Chen A poly(ionic liquid) was prepared from an ionic liquid monomer that was obtained by the reaction of 1-vinylimidazole, 4-vinyl-benzene chloride with 2,6-di-tert-butyl-4-methylphenol. The poly(ionic liquid) was mixed with K3[Fe(CN)6] and a 5 nm silica colloidal sol, carbonized at 900 °C for 4h, and sequentially treated with HNO3 and NaOH to remove the iron and silica to obtain nitrogen-doped graphitic carbon nanocapsules. The iron and silica acted as a graphitization catalyst and template, respectively. The nitrogen-doped graphitic carbon nanocapsules have a diameter of 50 nm and a wall thickness of 6 nm and have a high adsorption capacity and good recyclability for CO2 capture. The addition of SiO2 nanoparticles in the synthesis significantly increased the specific surface area from 100.4 to 865.7 m2 g−1 and the CO2 adsorption capacity from 0.76 to 2.14 mmol g−1.
Source: New Carbon Materials - Category: Chemistry Source Type: research