Synthesis of SiO2@carbon-graphene hybrids as anode materials of lithium-ion batteries

Publication date: August 2017 Source:New Carbon Materials, Volume 32, Issue 4 Author(s): Ling-hong Yin, Ming-bo Wu, Yan-peng Li, Gui-liang Wu, Yuan-kun Wang, Yang Wang SiO2@carbon-graphene (SiO2@C-G) hybrids with excellent electrochemical performance were prepared by the self-assembly of colloidal silica, sucrose and graphene oxide followed by ultrasonic-assisted hydrothermal and heat treatments. The mass ratio of silica to sucrose is crucial to the electrochemical performance of the resulting hybrids. A hybrid with a mass ratio of silica to sucrose of 0.15 shows the best reversible lithium storage performance, delivering an initial discharge capacity of 906 mAh g−1 and a capacity of 542 mAh g−1 at the 216th cycle at a current density of 100 mA g−1. The excellent cycling ability and high reversible capacity are attributed to a synergetic effect of the good conductivity of the SiO2@C-G hybrids, the small SiO2 particle size and the good dispersion of SiO2 nanoparticles in the hybrids. This methodology may provide a simple, scalable and eco-friendly strategy to prepare superior electrode materials from cheap and low electrical conductivity metal oxides.
Source: New Carbon Materials - Category: Chemistry Source Type: research