Selective Radical Fluorination of Tertiary Alkyl Halides at Room Temperature

AngewchemSelective Radical Fluorination of Tertiary Alkyl Halides at Room Temperature: Direct fluorination of tertiary alkyl bromides and iodides with Selectfluor is described. The halogen ‐exchange fluorination proceeds efficiently in acetonitrile at room temperature under metal‐free conditions...

Source: Organometallic Current - November 3, 2017 Category: Chemistry Tags: Fluorination Radical Reactions Source Type: blogs