Experimental and Computational Study of an Unexpected Iron ‐Catalyzed Carboetherification by Cooperative Metal and Ligand Substrate Interaction and Proton Shuttling

AngewchemExperimental and Computational Study of an Unexpected Iron ‐Catalyzed Carboetherification by Cooperative Metal and Ligand Substrate Interaction and Proton Shuttling: An iron ‐catalyzed cycloisomerization of allenols to deoxygenated pyranose glycals has been developed. Combined experimental and computational studies show that the iron complex exhibits a dual catalytic...

Source: Organometallic Current - October 25, 2017 Category: Chemistry Tags: Carboetherification Fe catalyzed Source Type: blogs