Cobalt versus Osmium: Control of Both trans and cis Selectivity in Construction of the EFG Rings of Pectenotoxin  4

AngewchemCobalt versus Osmium: Control of Both trans and cis Selectivity in Construction of the EFG Rings of Pectenotoxin  4: Catalytic oxidative cyclisation reactions have been employed for the synthesis of the E and F rings of the complex natural product target pectenotoxin  4. The choice of metal catalyst (cobalt‐ or osmium‐based)...

Source: Organometallic Current - October 23, 2017 Category: Chemistry Tags: Co catalyzed Natural products Source Type: blogs