Highly 2,3 ‐Selective Polymerization of Phenylallene and Its Derivatives with Rare‐Earth Metal Catalysts: From Amorphous to Crystalline Products

AngewchemHighly 2,3 ‐Selective Polymerization of Phenylallene and Its Derivatives with Rare‐Earth Metal Catalysts: From Amorphous to Crystalline Products: Rare ‐earth metal complexes (Flu‐CH2‐Py)Ln(CH2SiMe3)2(THF)n (Ln=Sc(1), Lu(2), Tm(3), Y(4) and Gd(5)), upon the activation of [Ph3C][B(C6F5)4] and AliBu3, were employed to catalyze the polymerization of...

Source: Organometallic Current - October 12, 2017 Category: Chemistry Tags: Ln catalyzed Polymerization Source Type: blogs