Gold(I) ‐Catalyzed Synthesis of Indenes and Cyclopentadienes: Access to (±)‐Laurokamurene B and the Skeletons of the Cycloaurenones and Dysiherbols

AngewchemGold(I) ‐Catalyzed Synthesis of Indenes and Cyclopentadienes: Access to (±)‐Laurokamurene B and the Skeletons of the Cycloaurenones and Dysiherbols: The formal (3+2) cycloaddition between terminal allenes and aryl or styryl gold(I) carbenes generated by a retro ‐Buchner reaction of 7‐substituted 1,3,5‐cycloheptatrienes led to indenes and cyclopentadienes,...

Source: Organometallic Current - October 12, 2017 Category: Chemistry Tags: Gold Catalysis Source Type: blogs