Regioselective Intermolecular Allylic C −H Amination of Disubstituted Olefins via Rhodium/π‐Allyl Intermediates

AngewchemRegioselective Intermolecular Allylic C −H Amination of Disubstituted Olefins via Rhodium/π‐Allyl Intermediates: A method for catalytic intermolecular allylic C −H amination of trans‐disubstituted olefins is reported. The reaction is efficient for a range of common nitrogen nucleophiles bearing one electron‐withdrawing...

Source: Organometallic Current - October 11, 2017 Category: Chemistry Tags: Allylic C-H amination Rh Catalyzed Source Type: blogs