Cooperative Effects between Chiral Cpx –Iridium(III) Catalysts and Chiral Carboxylic Acids in Enantioselective C−H Amidations of Phosphine Oxides

AngewchemCooperative Effects between Chiral Cpx –Iridium(III) Catalysts and Chiral Carboxylic Acids in Enantioselective C−H Amidations of Phosphine Oxides: An enantioselective C −H amidation of phosphine oxides by using an iridium(III) catalyst bearing an atropchiral cyclopentadienyl (Cpx) ligand is reported. A very strong cooperative effect between the chiral...

Source: Organometallic Current - October 11, 2017 Category: Chemistry Tags: C-H Amidation Ir catalyzed Source Type: blogs