Fluorine Effects on Group Migration via a Rhodium(V) Nitrenoid Intermediate

AngewchemFluorine Effects on Group Migration via a Rhodium(V) Nitrenoid Intermediate: An unprecedented rhodium(III) ‐catalyzed hydroarylation of α,α‐difluoromethylene alkynes with N‐pivaloxyl aroylamides through sequential C−H activation and aryl migration is detailed herein. A large array...

Source: Organometallic Current - October 11, 2017 Category: Chemistry Tags: Rh Catalyzed Source Type: blogs