Anion Relay Chemistry: Development of an Effective Diastereoselective [3 2] Annulation Tactic Exploiting an Aldol/Brook Rearrangement/Cyclization Cascade

AngewchemAnion Relay Chemistry: Development of an Effective Diastereoselective [3 2] Annulation Tactic Exploiting an Aldol/Brook Rearrangement/Cyclization Cascade: An effective [3+2] annulation tactic for the construction of diverse bicyclic compounds possessing highly functionalized cyclopentane rings has been developed employing soft ketone enolates as the initial...

Source: Organometallic Current - October 11, 2017 Category: Chemistry Tags: Aldol Reaction Brook Rearrangement Source Type: blogs