Synthesis of ent-[3]-Ladderanol: Development and Application of Intramolecular Chirality Transfer [2 2] Cycloadditions of Allenic Ketones and Alkenes

JacsSynthesis of ent-[3]-Ladderanol: Development and Application of Intramolecular Chirality Transfer [2 2] Cycloadditions of Allenic Ketones and Alkenes: An enantioselective synthesis ofent-[3]-ladderanol is presented. The ladderanes are an interesting class of molecules for their unique structure of fused cyclobutane rings as well as their perceived biological function of organism protection.

Source: Organometallic Current - October 11, 2017 Category: Chemistry Tags: Cycloaddition Source Type: blogs