α‐Carbonyl Cations in Sulfoxide‐Driven Oxidative Cyclizations

Angewchemα‐Carbonyl Cations in Sulfoxide‐Driven Oxidative Cyclizations: The selective, metal ‐free generation of α‐carbonyl cations from simple internal alkynes was accomplished by the addition of a sulfoxide to a densely substituted vinyl cation. The high reactivity of the...

Source: Organometallic Current - September 25, 2017 Category: Chemistry Tags: Oxidative Coupling Source Type: blogs