Spectrochemical study the effect of high energetic ionization radiation on Ru(III), Pd(II) and Hg(II) complexes

Publication date: Available online 14 March 2017 Source:Journal of Radiation Research and Applied Sciences Author(s): Samar A. Aly Complexes of Ru(III), Pd(II) and Hg(II) of hydrazone ligand have been prepared and characterized by 1H NMR, IR, elemental analyses, electronic spectra, magnetic moment, molar conductance and thermal analysis(DTA/TGA) before and after γ-irradiation. The result of 1H NMR before and after γ-irradiation confirms that the intensity of the peaks after γ-irradiation is larger than before γ-irradiation. Meanwhile, results of infrared spectra proved that γ-ray enhanced the stability of irradiated compounds as compared to non-irradiated compounds. Thermal studies of these chelates before and after γ-irradiation stable that the complexes of Ru(III) and Pd (II) after γ-irradiation are more thermal show than Hg(II) complexes before and after γ-irradiation.

Source: Journal of Radiation Research and Applied Sciences - March 13, 2017 Category: Physics Source Type: research