Molecular cathode and photocathode materials for hydrogen evolution in photoelectrochemical devices

Publication date: Available online 7 August 2015 Source:Journal of Photochemistry and Photobiology C: Photochemistry Reviews Author(s): Nicolas Queyriaux, Nicolas Kaeffer, Adina Morozan, Murielle Chavarot-Kerlidou, Vincent Artero Storage of solar energy in the form of readily available easy-to-handle fuels is the main bottleneck toward the development of a carbon-neutral alternative energy. Taking inspiration from natural systems, artificial photosynthesis is a technology to-be for efficiently converting the tremendous solar energy received every day on Earth into chemical energy, ie fuels. In particular, hydrogen production through light-driven water splitting is the subject of numerous investigations. We focus here on the construction of electrodes and photoelectrodes achieving H2 evolution, as components of photoelectrochemical (PEC) cells. In such devices, H2 evolution at the cathode or photocathode is combined with water oxidation to oxygen at the photoanode or anode. We review here the various molecular-based materials developed in this context with emphasis on those specifically exploiting the properties of Earth-abundant elements. Graphical abstract

Source: Journal of Photochemistry and Photobiology C: Photochemistry Reviews - August 9, 2015 Category: Chemistry Source Type: research